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SSL issues No Peer Certificate

I just picked up a Postitive SSL from ssls.com which is issued by Comodo.

In Openfire I went to TLS/SSL certificates

Created a CSR for my domain

Submitted CSR to cert authority

Downloaded my cert and added it to the Identity store which now shows a Status of CA Signed. RSA

Cert is authenticating properly in browser when logged in to https://chat.domain.com:9091

Pidgin does not trust the certificate.

When testing the cert using the following command I receive the following:

openssl s_client -connect chat.domain.com:5222 -starttls xmpp


no peer certificate available

No client certificate CA names sent

SSL handshake has read 480 bytes and written 128 bytes

New, (NONE), Cipher is (NONE)

Secure Renegotiation IS NOT supported

Compression: NONE

Expansion: NONE

Any ideas?