want to setting up chat server and android + iphone client with python apis can someone explain flow that how can i achieve that and provide sdk’s links for android , iphone and python ?
This is a question that can keep a small army of consultants busy for months. You will not be able to get a useful answer without doing a lot more work in defining conditions and expectations.
In essence, Openfire is an XMPP server. You are therefore likely looking for XMPP-capable libraries that are suitable for the environments that you are targeting. A starting point for this could be the website at xmpp.org, which lists various software projects.
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Adding to this answer:
Libraries: Smack + XmppFramework